xdg-autostart-generator: extend start timeout

The current start + stop timeouts for xdg autostart files are *very*
short with 5s. On a busy system this might be too easy to hit even in
unintended case.

Apparently, the intention here was to cut the shutdown logic short.
(https://github.com/systemd/systemd/issues/27919#issuecomment-1580576178)
Let's hence stick to the very short timeout for that (under the
assumption that apps are written in a safe enough style to not lose data
if killed too early). But for starting XGD autostrat services, use our
regular timeouts.

See: #27919

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